Search results for "Lipid bilayer mechanics"

showing 3 items of 3 documents

Stability of Asymmetric Lipid Bilayers Assessed by Molecular Dynamics Simulations

2009

The asymmetric insertion of amphiphiles into biological membranes compromises the balance between the inner and outer monolayers. As a result, area expansion of the receiving leaflet and curvature strain may lead to membrane permeation, shape changes, or membrane fusion events. We have conducted both atomistic and coarse-grained molecular dynamics simulations of dipalmitoyl-phosphatidylcholine (DPPC) bilayers to study the effect of an asymmetric distribution of lipids between the two monolayers on membrane stability. Highly asymmetric lipid bilayers were found to be surprisingly stable within the submicrosecond time span of the simulations. Even the limiting case of a monolayer immersed in …

12-DipalmitoylphosphatidylcholineLipid BilayersBiochemistryCatalysisColloid and Surface ChemistryCOARSE-GRAINED MODELSHAPE TRANSFORMATIONSMonolayerComputer SimulationLipid bilayer phase behaviorLipid bilayerChemistryBilayerLipid bilayer fusionBiological membraneGeneral ChemistryLipid bilayer mechanicsANTIMICROBIAL PEPTIDESCrystallographyMembraneTRANSMEMBRANE DISTRIBUTIONEGG PHOSPHATIDYLCHOLINEPhosphatidylcholinesPORE FORMATIONBiophysicsPRESSURE PROFILESMECHANOSENSITIVE CHANNELlipids (amino acids peptides and proteins)OCTYL GLUCOSIDEPHOSPHOLIPID-BILAYERSJournal of the American Chemical Society
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Elastic Properties and Line Tension of Self-Assembled Bilayer Membranes

2013

The elastic properties of a self-assembled bilayer membrane are studied using the self-consistent field theory, applied to a model system composed of flexible amphiphilic chains dissolved in hydrophilic polymeric solvents. Examining the free energy of bilayer membranes with different geometries allows us to calculate their bending modulus, Gaussian modulus, two fourth-order membrane moduli, and the line tension. The dependence of these parameters on the microscopic characteristics of the amphiphilic chain, characterized by the volume fraction of the hydrophilic component, is systematically studied. The theoretical predictions are compared with the results from a simple monolayer model, whic…

Materials scienceLipid BilayersNormal DistributionFOS: Physical sciencesNanotechnology02 engineering and technologyCondensed Matter - Soft Condensed MatterMolecular Dynamics Simulation01 natural sciencesQuantitative Biology::Subcellular Processes0103 physical sciencesMonolayerAmphiphileSoft matterPhysics - Biological Physics010306 general physicsElastic modulusPhysics::Biological PhysicsBilayerLinear elasticityCell MembraneLipid bilayer mechanics021001 nanoscience & nanotechnologyElasticityCondensed Matter::Soft Condensed MatterMembraneNonlinear DynamicsChemical physicsBiological Physics (physics.bio-ph)ThermodynamicsSoft Condensed Matter (cond-mat.soft)0210 nano-technology
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The role of the hydrophobic force in bilayer adhesion and fusion

1991

The Surface Forces Apparatus technique was used for measuring the adhesion, deformation, and fusion of bilayers supported on mica. The technique allows the molecular rearrangements to be followed in real time during the fusion process, and the most important forces involved to be identified. The adhesion between two bilayers can be increased by two orders of magnitude if they are thinned so as to expose more hydrophobic groups. For all the bilayer systems studied a single basic fusion mechanism was found in which the bilayers do not “overcome” the short-range repulsive steric-hydration forces; instead, local bilayer deformations allow these repulsive forces to be “bypassed”. The results fur…

FusionPolymers and PlasticsChemistryBilayerOrganic ChemistryNanotechnologySurface forces apparatusAdhesionLipid bilayer mechanicsInterbilayer forces in membrane fusionCondensed Matter PhysicsChemical physicsMaterials ChemistryMicaFusion mechanismMakromolekulare Chemie. Macromolecular Symposia
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